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Document Details
Document Type
:
Article In Journal
Document Title
:
Thermal fragmentation of spirodithiohydantoins: A novel route to NHCs
Thermal fragmentation of spirodithiohydantoins: A novel route to NHCs
Document Language
:
English
Abstract
:
Spirodithiohydantoins undergo a two-step thermal fragmentation affording zwitterionic betaine intermediates and N-heterocyclic carbenes (NHCs) respectively. Such reactions are novel, occur under mild conditions and give NHCs in high yield and purity. This phenomenon was studied using various spectroscopic techniques and control experiments with elemental sulfur. Quantum chemical calculations were employed to provide a deeper understanding of such transformations.
ISSN
:
2046-2069
Journal Name
:
RSC ADVANCES
Volume
:
3
Issue Number
:
6
Publishing Year
:
1434 AH
2013 AD
Article Type
:
Article
Added Date
:
Thursday, July 20, 2017
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
D Jishkariani
Jishkariani, D
Researcher
c (Hall
(Hall, c
Researcher
A Oliferenko
Oliferenko, A
Researcher
b Tomlin
Tomlin, b
Researcher
p Steel
Steel, p
Researcher
A Katritzky
Katritzky, A
Researcher
Files
File Name
Type
Description
42122.pdf
pdf
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